Mass Spectra of Ferrocenophanes

POSITIVE AND NEGATIVE ION MASS SPECTRA OF RING - SUBSTITUTED NITROBENZENES

The 70 ev positive and negative ion mass spectra of ring-substituted nitrobenzenes were studied. The influence of the substituent group on the fragmentation modes of the molecular ions is discussed. The effect of pressure in the formation of negative ions was also studied. As expected, the ratio of fragment ions to negative molecular ions decreased with increasing pressure in ion source.

Modelling CDA mass spectra

We present the initial results from a simulation of ion behaviour within Cassini’s cosmic dust analyser (CDA) instrument, using an inhouse ion dynamics code. This work is to enable and enhance the detailed interpretation of dust impact ionisation mass spectra returned from the Saturnian system. Early work has already provided insights into the properties of the impact plasma in both lowand high...

accurate-mass spectra

Stereochemical Alignment in Triphospha[3]ferrocenophanes

A series of triphospha[3]ferrocenophanes of the type Fe(C5 H4 -PtBu)2 PX with X=H, F, Cl, Br, I, NEt2 , tBu has been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. Despite having three stereogenic centers, the selective formation of a reduced number of diastereomers (either one or two) has been observed for these ferrocenophanes. Theoretical calculations...

The Invariant Mass Spectra Profile

Two possible reasons for the narrow peak observation in the invariant mass spectrum of the pK 0 s close to 1.54 GeV/c 2 are discussed.